Synthetic strategies towards mechanically interlocked oligomers and polymers
Author(s)
Perez, Nadia Hoyas
Lewis, James EM
Type
Journal Article
Abstract
Mechanically interlocked molecules have fascinated chemists for decades. Initially a tantalising synthetic challenge, interlocked molecules have continued to capture the imagination for their aesthetics and, increasingly, for their potential as molecular machines and use in materials applications. Whilst preliminary statistical attempts to prepare these molecules were exceedingly inefficient, a raft of template-directed strategies have now been realised, providing a vast toolbox from which chemists can access interlocked structures in excellent yields. For many envisaged applications it is desirable to move away from small, discrete interlocked molecules and turn to oligomers and polymers instead, either due to the need for multiple mechanical bonds within the desired material, or to exploit an extended scaffold for the organisation and arrangement of individual mechanically interlocked units. In this tutorial-style review we outline the synthetic strategies that have been employed for the synthesis of mechanically interlocked oligomers and polymers, including oligo-/polymerisation of (pseudo)interlocked precursors, metal–organic self-assembly, the use of orthogonal template motifs, iterative approaches and grafting onto polymer backbones.
Date Issued
2020-09-21
Date Acceptance
2020-08-20
Citation
Organic and Biomolecular Chemistry, 2020, 18 (35), pp.6757-6780
ISSN
1477-0520
Publisher
Royal Society of Chemistry
Start Page
6757
End Page
6780
Journal / Book Title
Organic and Biomolecular Chemistry
Volume
18
Issue
35
Copyright Statement
This journal is © The Royal Society of Chemistry 2020Open Access Article. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence
License URL
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000571281400001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Physical Sciences
Chemistry, Organic
Chemistry
METAL-ORGANIC FRAMEWORKS
EVERY STRUCTURAL UNIT
CYCLODEXTRIN-BASED POLYROTAXANES
SIDE-CHAIN POLYROTAXANES
HIGH-YIELD SYNTHESIS
CROWN-ETHER WHEEL
ONE-POT SYNTHESIS
CONJUGATED POLYROTAXANES
MOLECULAR NECKLACE
TEMPLATE SYNTHESIS
Publication Status
Published