Relationship between fill factor and light intensity in solar cells based on organic disordered semiconductors: The role of tail states
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Supporting information
Accepted version
Author(s)
Type
Journal Article
Abstract
The origin of the relationship between fill factor (FF) and light intensity (I) in organic disordered-semiconductor-based solar cells is studied. An analytical model describing the balance between transport and recombination of charge carriers, parameterized with a factor,
Γ
m
, is introduced to understand the FF-I relation, where higher values of
Γ
m
correlate to larger FFs. Comparing the effects of direct and tail-state-mediated recombination on the FF-I plot, we find that, for low-mobility systems, direct recombination with constant transport mobility can deliver only a negative dependence of
Γ
m
,
dir
on light intensity. By contrast, tail-state-mediated recombination with trapping and detrapping processes can produce a positive
Γ
m
,
t
versus sun dependency. The analytical model is validated by numerical drift-diffusion simulations. To further validate our model, two material systems that show opposite FF-I behavior are studied: poly{4,8-bis[5-(2-ethylhexyl)thiophen-2-yl]benzo[1,2-b;4,5-b′]dithiophene-2,6-diyl-alt-[4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl]} (PTB7-Th):[6,6]-phenyl-
C
71
-butyric acid methyl ester (
PC
71
BM) devices show a negative FF-I relation, while PTB7-Th:(5Z,5′Z)-5,5′-{[7,7′ -(4,4,9,9-tetraoctyl-4,9-dihydro-s-indaceno[1,2-b:5,6-b′]dithiophene-2,7-diyl)bis(benzo[c][1,2,5]thiadiazole-7,4-diyl)]bis(methanylylidene)}bis(3-ethyl-2-thioxothiazolidin-4-one) (O-IDTBR) devices show a positive correlation. Optoelectronic measurements show that the O-IDTBR device presents a higher ideality factor, stronger trapping and detrapping behavior, and a higher density of trap states, relative to the
PC
71
BM device, supporting the theoretical model. This work provides a comprehensive understanding of the correlation between FF and light intensity for disordered-semiconductor-based solar cells.
Γ
m
, is introduced to understand the FF-I relation, where higher values of
Γ
m
correlate to larger FFs. Comparing the effects of direct and tail-state-mediated recombination on the FF-I plot, we find that, for low-mobility systems, direct recombination with constant transport mobility can deliver only a negative dependence of
Γ
m
,
dir
on light intensity. By contrast, tail-state-mediated recombination with trapping and detrapping processes can produce a positive
Γ
m
,
t
versus sun dependency. The analytical model is validated by numerical drift-diffusion simulations. To further validate our model, two material systems that show opposite FF-I behavior are studied: poly{4,8-bis[5-(2-ethylhexyl)thiophen-2-yl]benzo[1,2-b;4,5-b′]dithiophene-2,6-diyl-alt-[4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl]} (PTB7-Th):[6,6]-phenyl-
C
71
-butyric acid methyl ester (
PC
71
BM) devices show a negative FF-I relation, while PTB7-Th:(5Z,5′Z)-5,5′-{[7,7′ -(4,4,9,9-tetraoctyl-4,9-dihydro-s-indaceno[1,2-b:5,6-b′]dithiophene-2,7-diyl)bis(benzo[c][1,2,5]thiadiazole-7,4-diyl)]bis(methanylylidene)}bis(3-ethyl-2-thioxothiazolidin-4-one) (O-IDTBR) devices show a positive correlation. Optoelectronic measurements show that the O-IDTBR device presents a higher ideality factor, stronger trapping and detrapping behavior, and a higher density of trap states, relative to the
PC
71
BM device, supporting the theoretical model. This work provides a comprehensive understanding of the correlation between FF and light intensity for disordered-semiconductor-based solar cells.
Date Issued
2020-08-13
Date Acceptance
2020-07-02
Citation
Physical Review Applied, 2020, 14, pp.024034 – 1-024034 – 17
ISSN
2331-7019
Publisher
American Physical Society
Start Page
024034 – 1
End Page
024034 – 17
Journal / Book Title
Physical Review Applied
Volume
14
Copyright Statement
Copyright 2020, American Physical Society
Sponsor
Commission of the European Communities
Identifier
https://journals.aps.org/prapplied/abstract/10.1103/PhysRevApplied.14.024034
Grant Number
742708
Subjects
02 Physical Sciences
09 Engineering
Publication Status
Published
Date Publish Online
2020-08-13