Using dicyanoanthracene triflates as superior precursors: modifying properties by sterically hindered aryl substituents
File(s)
Accepted version
Author(s)
Gloecklhofer, Florian
Kautny, Paul
Fritz, Patrick
Stoeger, Berthold
Froehlich, Johannes
Type
Journal Article
Abstract
The preparation of 9,10‐dicyanoanthracene triflates is reported. Taking advantage of the high reactivity of these precursors in Suzuki coupling reactions, sterically hindered substituents were introduced. The impact of the substituents on the crystallographic and photophysical properties was investigated. The results highlight the usefulness of the new triflate derivatives and the substituents for the development of 9,10‐dicyanoanthracene‐based materials.
Date Issued
2017-02-13
Date Acceptance
2016-12-05
Citation
Chemphotochem, 2017, 1 (2), pp.51-55
ISSN
2367-0932
Publisher
Wiley-Blackwell
Start Page
51
End Page
55
Journal / Book Title
Chemphotochem
Volume
1
Issue
2
Copyright Statement
© 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is the peer reviewed version of the following article, which has been published in final form at https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/cptc.201600018. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000406602100003&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Physical Sciences
Chemistry, Physical
Chemistry
cross-coupling reactions
cyanides
fluorescence
fused-ring systems
steric hindrance
LIGHT-EMITTING-DIODES
ANTHRACENE-DERIVATIVES
EFFICIENCY
DESIGN
Publication Status
Published
Date Publish Online
2016-12-05