Pyrolysis and spontaneous ignition of wood under transient
irradiation: experiments and a-priori predictions
irradiation: experiments and a-priori predictions
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Article In Press
Author(s)
vermesi, I
Didomizio, M
richter, F
Weckman, E
Rein, G
Type
Journal Article
Abstract
Wood is a material widely used in the built environment, but its flammability and response to fire are a
disadvantage. Therefore, it is essential to have substantial knowledge of the behavior of wood undergoing
external heating such as in a fire. The majority of studies in the literature use constant irradiation. Although
this assumption simplifies both modelling and experimental endeavors, it is important to assess the behavior
of materials under more comprehensive heating scenarios which might challenge the validity of solid-phase
ignition criteria developed previously. These criteria are evaluated here for the spontaneous ignition under
transient irradiation by combining experimental measurements and a-priori predictions from a model of heat
transfer and pyrolysis. We have applied a two-step transient irradiation in the cone calorimeter in the form
of a growth curve followed by a threshold of constant irradiation. We used white spruce samples of size 100
x 100 mm thickness of 38 mm measured the temperature at different depths and the mass loss. A one di-
mensional model written in the open source code Gpyro is used to predict the pyrolysis behavior. The model
has a chemical scheme in which the virgin components of wood (hemicellulose, cellulose, lignin) become
active, then decompose in two competing reactions: char and gas, and tar. The kinetic parameters, as well
as the thermal properties of the wood and char are taken from the literature, while
ρ
and moisture content
are measured experimentally. A priori predictions of the temperature, made prior to the experiments, show
excellent agreement with the measurements, being within the experimental uncertainty range. The mass loss
rate (MLR) predictions are qualitatively similar to the measurements, but there is a large uncertainty in the
measurements. For a-posteriori simulations, certain parameters are changed after having access to the mea-
surements to improve the simulations. We found that the heat of reaction for exothermic reactions has no
influence, the reaction order of the char reaction influences the MLR, whereas the reaction order of the tar re-
action is important for temperatures and MLR. The in-depth absorption is very important in cone calorimeter
experiments. Also, we perform an evaluation of the solid phase ignition criteria. The ignition criteria found in
the literature are the critical temperature, the critical mass loss rate, the critical heat flux, and the time-energy
squared correlation. We find that neither criteria is a consistent indicator of ignition. These results help un-
derstand the spontaneous ignition of wood subjected to transient irradiation and identify strengths and gaps
in the topic.
disadvantage. Therefore, it is essential to have substantial knowledge of the behavior of wood undergoing
external heating such as in a fire. The majority of studies in the literature use constant irradiation. Although
this assumption simplifies both modelling and experimental endeavors, it is important to assess the behavior
of materials under more comprehensive heating scenarios which might challenge the validity of solid-phase
ignition criteria developed previously. These criteria are evaluated here for the spontaneous ignition under
transient irradiation by combining experimental measurements and a-priori predictions from a model of heat
transfer and pyrolysis. We have applied a two-step transient irradiation in the cone calorimeter in the form
of a growth curve followed by a threshold of constant irradiation. We used white spruce samples of size 100
x 100 mm thickness of 38 mm measured the temperature at different depths and the mass loss. A one di-
mensional model written in the open source code Gpyro is used to predict the pyrolysis behavior. The model
has a chemical scheme in which the virgin components of wood (hemicellulose, cellulose, lignin) become
active, then decompose in two competing reactions: char and gas, and tar. The kinetic parameters, as well
as the thermal properties of the wood and char are taken from the literature, while
ρ
and moisture content
are measured experimentally. A priori predictions of the temperature, made prior to the experiments, show
excellent agreement with the measurements, being within the experimental uncertainty range. The mass loss
rate (MLR) predictions are qualitatively similar to the measurements, but there is a large uncertainty in the
measurements. For a-posteriori simulations, certain parameters are changed after having access to the mea-
surements to improve the simulations. We found that the heat of reaction for exothermic reactions has no
influence, the reaction order of the char reaction influences the MLR, whereas the reaction order of the tar re-
action is important for temperatures and MLR. The in-depth absorption is very important in cone calorimeter
experiments. Also, we perform an evaluation of the solid phase ignition criteria. The ignition criteria found in
the literature are the critical temperature, the critical mass loss rate, the critical heat flux, and the time-energy
squared correlation. We find that neither criteria is a consistent indicator of ignition. These results help un-
derstand the spontaneous ignition of wood subjected to transient irradiation and identify strengths and gaps
in the topic.
Date Issued
2017-05-13
Date Acceptance
2017-03-15
Citation
Fire Safety Journal, 2017, 91, pp.218-225
ISSN
1873-7226
Publisher
Elsevier
Start Page
218
End Page
225
Journal / Book Title
Fire Safety Journal
Volume
91
Copyright Statement
© 2017 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/BY/4.0/).
License URL
Sponsor
EPSRC
Grant Number
EP/M506345/1
Subjects
Science & Technology
Technology
Engineering, Civil
Materials Science, Multidisciplinary
Engineering
Materials Science
Modelling
Ignition
Heat transfer
Pyrolysis
BIOMASS
0904 Chemical Engineering
Civil Engineering
Publication Status
Published