High performance H2-Mn regenerative fuel cells through an improved positive electrode morphology
File(s)Rubio-Garcia-2023-High Performance H-2-Mn Rege.pdf (1.6 MB)
Published version
Author(s)
Type
Journal Article
Abstract
The effective scaling-up of redox flow batteries (RFBs) can be facilitated upon lowering the capital costs. The application of ubiquitous manganese along with hydrogen (known as H2−Mn regenerative fuel cells (RFC)) is seen as an effective solution for this purpose. Here, we aim to evaluate different positive electrodes so as to improve the key performance metrics of the H2/Mn RFC, namely electrolyte utilization, energy efficiency, and peak power densities. Commercially available carbon paper and graphite felt are used to show that the latter provides better key performance indicators (KPIs), which is consistent with the results reported for standard all-vanadium RFBs in the literature. Even better KPIs are obtained when an in-house carbon catalyst layer (CCL) is employed in combination with graphite felt electrodes (e.g., more than 80% energy efficiency, >0.5 W cm−2 peak power density and electrolyte utilization of 20 Ah L−1 for felt and carbon metal fabric (CMF), prepared by means of electrospinning and carbonization, in comparison with about 75% energy efficiency 0.45 W cm−2 peak power density and 11 Ah L−1 electrolyte utilization for felt on its own). It is envisaged that if the electrochemical performance of CCLs can be optimized then it could open up new opportunities for the commercial exploitation of H2−Mn systems.
Date Issued
2023-02
Date Acceptance
2023-01-25
Citation
Batteries, 2023, 9 (2)
ISSN
2313-0105
Publisher
MDPI AG
Journal / Book Title
Batteries
Volume
9
Issue
2
Copyright Statement
© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
License URL
Identifier
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000938255000001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=a2bf6146997ec60c407a63945d4e92bb
Subjects
CATALYST
Electrochemistry
electrodes
electrospinning
Energy & Fuels
ENERGY-STORAGE
hydrogen
manganese
Materials Science
Materials Science, Multidisciplinary
Physical Sciences
redox flow battery
REDOX FLOW BATTERY
regenerative fuel cell
Science & Technology
Technology
Publication Status
Published
Article Number
108
Date Publish Online
2023-02-03