Film Formation of Non-Planar Phthalocyanines on Copper (I) Iodide
File(s)2016_RSC_Advances_Ramadan.pdf (1.19 MB)
Published version
Author(s)
Alexandra J Ramadan,
Fearn, S
Tim Jones,
Sandrine Heutz
Luke A. Rochford
Type
Journal Article
Abstract
Structural templating is frequently used in organic photovoltaic devices to control the properties of the functional layers
and therefore improve efficiencies. Modification of the substrate temperatures has also been shown to impact the
structure and morphology of phthalocyanine thin films. Here we combine templating by copper iodide and high substrate
temperature growth and study its effect on the structure and morphology of two different non-planar phthalocyanines,
chloroaluminium (ClAlPc) and vanadyl (VOPc) phthalocyanine. X-ray diffraction, atomic force microscopy and low energy
ion scattering show that both the morphology and the structure of the films are starkly different in every case, highlighting
the versatility of phthalocyanine film growth.
and therefore improve efficiencies. Modification of the substrate temperatures has also been shown to impact the
structure and morphology of phthalocyanine thin films. Here we combine templating by copper iodide and high substrate
temperature growth and study its effect on the structure and morphology of two different non-planar phthalocyanines,
chloroaluminium (ClAlPc) and vanadyl (VOPc) phthalocyanine. X-ray diffraction, atomic force microscopy and low energy
ion scattering show that both the morphology and the structure of the films are starkly different in every case, highlighting
the versatility of phthalocyanine film growth.
Date Issued
2016-09-26
Date Acceptance
2016-09-23
Citation
RSC Advances, 2016, 6 (97), pp.95227-95231
ISSN
2046-2069
Publisher
Royal Society of Chemistry
Start Page
95227
End Page
95231
Journal / Book Title
RSC Advances
Volume
6
Issue
97
Copyright Statement
© The Royal Society of Chemistry 2016
Publication Status
Published