Core-shell carbon-polymer quantum dot passivation for near infrared perovskite light emitting diodes
File(s)Tountas_2022_J._Phys._Photonics_4_034007.pdf (7.59 MB)
Published version
Author(s)
Tountas, Marinos
Soultati, Anastasia
Armadorou, Konstantina-Kalliopi
Ladomenou, Kalliopi
Landrou, Georgios
Type
Journal Article
Abstract
High-performance perovskite light-emitting diodes (PeLEDs) require a high quality perovskite emitter and appropriate charge transport layers to facilitate charge injection and transport within the device. Solution-processed n-type metal oxides represent a judicious choice for the electron transport layer (ETL); however, they don't always present suitable surface properties and energetics in order to be compatible with the perovskite emitter. Moreover, the emitter itself exhibits poor nanomorphology and defect traps that compromise the device performance. Here we modulate the surface properties and interface energetics of the tin oxide (SnO2) ETL with the perovskite emitter by using an amino functionalized difluoro{2-[1-(3,5-dimethyl-2H-pyrrol-2-ylidene-N)ethyl]-3,5-dimethyl-1H-pyrrolato-N}boron (BDP) compound and passivate the defects present in the perovskite with carbon-polymer core-shell quantum dots (PCDs) inserted into the perovskite precursor. Both these approaches synergistically improve the perovskite layer nanomorphology and enhance the radiative recombination. These properties resulted in the fabrication of near infrared (NIR) PeLEDs based on formamidinium lead iodide (FAPbI3) with a high radiance of 92 W sr-1 m-2, an external quantum efficiency (EQE) of 14% and reduced efficiency roll-off.
Date Issued
2022-07-01
Date Acceptance
2022-06-17
Citation
Journal of Physics: Photonics, 2022, 4 (3)
ISSN
2515-7647
Publisher
IOP Publishing
Journal / Book Title
Journal of Physics: Photonics
Volume
4
Issue
3
Copyright Statement
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Although reasonable endeavours have been taken to obtain all necessary permissions from third parties to include their copyrighted content within this article, their full citation and copyright line may not be present in this Accepted Manuscript version. Before using any content from this article, please refer to the Version of Record on IOPscience once published for full citation and copyright details, as permission may be required. All third party content is fully copyright protected, and is not published on a gold open access basis under a CC BY licence, unless that is specifically stated in the figure caption in the Version of Record.
this work may be used
under the terms of the
Creative Commons
Attribution 4.0 licence.
Any further distribution
of this work must
maintain attribution to
the author(s) and the title
of the work, journal
citation and DOI.
Although reasonable endeavours have been taken to obtain all necessary permissions from third parties to include their copyrighted content within this article, their full citation and copyright line may not be present in this Accepted Manuscript version. Before using any content from this article, please refer to the Version of Record on IOPscience once published for full citation and copyright details, as permission may be required. All third party content is fully copyright protected, and is not published on a gold open access basis under a CC BY licence, unless that is specifically stated in the figure caption in the Version of Record.
License URL
Identifier
https://iopscience.iop.org/article/10.1088/2515-7647/ac79e9/meta
Publication Status
Published
Article Number
ARTN 034007
Date Publish Online
2022-06-17