Statistical mechanics of 'Unwanted Electroactuation' in nanoporous supercapacitors
File(s)Manuscript.pdf (1.09 MB)
Accepted version
Author(s)
Rochester, Christopher C
Pruessner, Gunnar
Kornyshev, Alexei A
Type
Journal Article
Abstract
Nanoporous electrodes have the potential to increase the surface electrode interfacial area and the stored energy density of a supercapacitor. However, structural deformation of the electrode can become apparent when the size of the pore is comparable to the size of a charging ion. After many cycles this could cause wear and degradation. We present a theoretical study of this ‘Unwanted Electroactuation’ in a carbon electrode wetted with an ionic liquid. We incorporate changes of the carbon-carbon bond length due to electrochemical doping of the pore walls and steric effects related to counterion insertion into the pore via a modified Ising model of charge storage. When considering the total electrode deformation these effects either complement or compete with each other, depending on the polarisation of the electrode. Our model shows qualitative agreement with the features of the experimentally observed expansion caused by variation of electrode potential.
Date Issued
2015-08-20
Date Acceptance
2015-04-10
Citation
Electrochimica Acta, 2015, 174, pp.978-984
ISSN
0013-4686
Publisher
Elsevier
Start Page
978
End Page
984
Journal / Book Title
Electrochimica Acta
Volume
174
Copyright Statement
© 2015 Elsevier Ltd. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000359873400124&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Grant Number
EP/H004319/1
EP/K039946/1
Subjects
Science & Technology
Physical Sciences
Electrochemistry
Supercapacitors
Electroactuation
Nanoporous Carbon
Ionic Liquids
CARBIDE-DERIVED CARBON
ELECTROCHEMICAL CAPACITORS
DIMENSIONAL CHANGES
CHARGE STORAGE
NANOTUBES
ACTUATORS
Publication Status
Published
Date Publish Online
2015-06-09