Controlled Low-Strength Materials Containing Solid Waste from Minerals Bioleaching
Author(s)
Bouzalakos, Steve
Type
Thesis
Abstract
Sustainable treatment and disposal of mine waste is a serious environmental issue faced by
the mining industry worldwide. Conventional methods of mine waste management
predominantly involve indefinite retention in engineered tailings dams. The cost and liability
of such surface storage facilities have increased significantly in recent years as an outcome of
stringent environmental legislation and mine closure requirements gradually transforming the
economics of mine waste disposal. Backfill methods, particularly cemented paste backfill, are
increasingly perceived as sustainable, environmentally friendly and cost-effective alternatives
as they put waste material to practical use. Controlled low-strength materials (CLSM) offer
an effective and practical alternative to similar analogues – requiring minimal compaction,
being self-levelling and excavatable in the future if necessary.
The aim of this research was to develop and evaluate CLSM, previously un-tested at mines,
in which novel utilisation of bioleach waste is maximised and Portland cement content
minimised while satisfying performance requirements for classification as CLSM.
Leachability of toxic substances was minimised through encapsulating CLSM within a
coating of relatively inert CLSM. Formulation and optimisation of CLSM using statistical
mixture design and response surface analysis has ensured proper understanding of component
interactions and influence on mechanical strength with a minimum amount of experiments.
Optimised CLSM formulations were tested for their mechanical, physical, micro-structural,
mineralogical and chemical properties. Effects of encapsulation were determined by
assessing chemical leaching. The work indicated that bioleach waste could be beneficially reformed
as CLSM of appropriate compressive strength for application in groundwork as loadbearing
materials. Porosity and hydraulic conductivity were correspondingly high.
Leachability of arsenic, barium, chromium, lead and zinc was significant (levels varied
depending on waste type). Encapsulation significantly reduced leachability indicating
promising potential for implementation of this technology in the mining industry.
The research presented in this thesis substantiated the need for, and potential of, sustainable
novel alternative technologies such as CLSM to augment future waste management strategies
in the mining industry via safe emplacement of solid bioleach waste in the sub-surface.
the mining industry worldwide. Conventional methods of mine waste management
predominantly involve indefinite retention in engineered tailings dams. The cost and liability
of such surface storage facilities have increased significantly in recent years as an outcome of
stringent environmental legislation and mine closure requirements gradually transforming the
economics of mine waste disposal. Backfill methods, particularly cemented paste backfill, are
increasingly perceived as sustainable, environmentally friendly and cost-effective alternatives
as they put waste material to practical use. Controlled low-strength materials (CLSM) offer
an effective and practical alternative to similar analogues – requiring minimal compaction,
being self-levelling and excavatable in the future if necessary.
The aim of this research was to develop and evaluate CLSM, previously un-tested at mines,
in which novel utilisation of bioleach waste is maximised and Portland cement content
minimised while satisfying performance requirements for classification as CLSM.
Leachability of toxic substances was minimised through encapsulating CLSM within a
coating of relatively inert CLSM. Formulation and optimisation of CLSM using statistical
mixture design and response surface analysis has ensured proper understanding of component
interactions and influence on mechanical strength with a minimum amount of experiments.
Optimised CLSM formulations were tested for their mechanical, physical, micro-structural,
mineralogical and chemical properties. Effects of encapsulation were determined by
assessing chemical leaching. The work indicated that bioleach waste could be beneficially reformed
as CLSM of appropriate compressive strength for application in groundwork as loadbearing
materials. Porosity and hydraulic conductivity were correspondingly high.
Leachability of arsenic, barium, chromium, lead and zinc was significant (levels varied
depending on waste type). Encapsulation significantly reduced leachability indicating
promising potential for implementation of this technology in the mining industry.
The research presented in this thesis substantiated the need for, and potential of, sustainable
novel alternative technologies such as CLSM to augment future waste management strategies
in the mining industry via safe emplacement of solid bioleach waste in the sub-surface.
Date Issued
2008
Date Awarded
2008-10
Copyright Statement
Attribution NoDerivatives 4.0 International Licence (CC BY-ND)
Advisor
Dudeney, Bill
Cheeseman, Chris
Sponsor
European Commission under the Sixth Framework Programme for Research and Development
Creator
Bouzalakos, Steve
Publisher Department
Department of Earth Science and Engineering
Publisher Institution
Imperial College London
Qualification Level
Doctoral
Qualification Name
Doctor of Philosophy (PhD)