Ultrafast polarization switching in BaTiO3 by photoactivation of its ferroelectric and central modes
File(s)main-5.pdf (7.08 MB)
Accepted version
Author(s)
Gu, Fangyuan
Tangney, Paul
Type
Journal Article
Abstract
We use molecular dynamics simulations with machine-learned atomistic force fields to simulate photoexcitation of by a femtosecond laser pulse whose photon energy exceeds the optical gap. We demonstrate selective displacive excitation of coherent zone-center ferroelectric mode phonons and of the strongly anharmonic central mode. We show that the direction of $\pp$ can either be reversed by a pulse in hundreds of femtoseconds or, on a longer time scale and when combined with a weak field, switched to any one of its symmetry-equivalent directions.
Date Issued
2024-07-01
Date Acceptance
2024-07-01
Citation
Physical Review B: Condensed Matter and Materials Physics, 2024, 110 (1)
ISSN
2469-9950
Publisher
American Physical Society
Journal / Book Title
Physical Review B: Condensed Matter and Materials Physics
Volume
110
Issue
1
Copyright Statement
Copyright This paper is embargoed until publication. Once published the author’s accepted manuscript will be made available under a CC-BY License in accordance with Imperial’s Research Publications Open Access policy (www.imperial.ac.uk/oa-policy).
License URL
Identifier
https://journals.aps.org/prb/abstract/10.1103/PhysRevB.110.014307
Publication Status
Published
Article Number
014307
Date Publish Online
2024-07-16