Superhydrophobic surfaces with recirculating interfacial flow due to surfactants are 'effectively' immobilised
Author(s)
Crowdy, Darren
Rodriguez-Broadbent, Henry
Type
Journal Article
Abstract
At high surface Péclet numbers, it is common to associate the presence of surfactants with surface immobilization, where a free surface becomes indistinguishable from a no-slip surface. A different mechanism has recently been proposed for longitudinal shear flow along a unidirectional trench (Baier & Hardt, J. Fluid Mech., vol. 949, 2022, A34) wherein, at high Marangoni numbers, the meniscus spanning the finite-length trench becomes a constant-shear-stress surface due to contamination by incompressible surfactant. That model predicts recirculating interfacial flows on the meniscus, a phenomenon that has been observed experimentally (Song et al., Phys. Rev. Fluids, vol. 3, issue 3, 2018, 033303). By finding an explicit solution to the constant-shear-stress model at all protrusion angles and calculating the effective slip length for a dilute mattress of such surfactant-laden trenches, we show that those effective slip lengths are almost indistinguishable from those for a surface whose menisci have the same deflection but have been completely immobilized (i.e. they are no-slip surfaces). This means that, despite the presence of non-trivial recirculating vortical flows on the menisci, the aggregate slip characteristics of such surfaces are that they have been effectively immobilized. This surprising result underscores the need for caution in comparing theory with experiments based on effective slip properties alone.
Date Issued
2023-02-10
Date Acceptance
2023-01-03
Citation
Journal of Fluid Mechanics, 2023, 956, pp.1-11
ISSN
0022-1120
Publisher
Cambridge University Press
Start Page
1
End Page
11
Journal / Book Title
Journal of Fluid Mechanics
Volume
956
Copyright Statement
© The Author(s), 2023. Published by Cambridge University Press
This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution and reproduction, provided the original article is properly cited.
This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted re-use, distribution and reproduction, provided the original article is properly cited.
License URL
Identifier
https://www.cambridge.org/core/journals/journal-of-fluid-mechanics/article/superhydrophobic-surfaces-with-recirculating-interfacial-flow-due-to-surfactants-are-effectively-immobilized/C7B3BBFC2F63BED6E4A99EF854D46108
Publication Status
Published
Article Number
R3
Date Publish Online
2023-01-30